Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 536-90-3, Name is 3-Methoxyaniline, molecular formula is , belongs to amides-buliding-blocks compound. In a document, author is Xiang, Yang, Computed Properties of C7H9NO.
Sustainable Alkylation of Unactivated Esters and Amides with Alcohols Enabled by Manganese Catalysis
The first example of manganese-catalyzed C-alkylation of the carboxylic acid derivatives is reported. The bench-stable homogeneous manganese complex enables the transformation of the renewable alcohol and carboxylic acid derivative feedstock to higher value esters and amides. The reaction operates via hydrogen autotransfer and ideally produces water as the only side product. Importantly, aliphatic-, benzylic-, and heterocyclic-containing alcohols can be used as alkylating reagents, eliminating the need for mutagenic alkyl halides.
If you are hungry for even more, make sure to check my other article about 536-90-3, Computed Properties of C7H9NO.