Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Zhang, Kai, once mentioned the application of 6582-52-1, Name is 2,2′-Methylenedianiline, molecular formula is C13H14N2, molecular weight is 198.2637, MDL number is MFCD01109641, category is amides-buliding-blocks. Now introduce a scientific discovery about this category, Category: amides-buliding-blocks.
Rhodium(III)-Catalyzed Synthesis of Skipped Enynes via C(sp(3))-H Alkynylation of Terminal Alkenes
The Rh-III-catalyzed allylic C-H alkynylation of non-activated terminal alkenes leads selectively to linear 1,4-enynes at room-temperature. The catalytic system tolerates a wide range of functional groups without competing functionalization at other positions. Similarly, the vinylic C-H alkynylation of alpha,beta- and beta,gamma- unsaturated amides gives conjugated Z-1,3-enynes and E-enediynes.
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