Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 73942-87-7, Name is 7,8-Dimethoxy-1,3-dihydro-2H-3-benzazepin-2-one, molecular formula is C12H13NO3. In an article, author is Ludmerczki, Robert,once mentioned of 73942-87-7, Safety of 7,8-Dimethoxy-1,3-dihydro-2H-3-benzazepin-2-one.
Recyclable Oxofluorovanadate-Catalyzed Formylation of Amines by Reductive Functionalization of CO2 with Hydrosilanes
An efficient method has been developed for the reductive amination of CO2 by using readily available and recyclable oxofluorovanadates as catalysts. Various amines are transformed into the desired N-formylated products in moderate to excellent yields at room temperature in the presence of phenylsilane. Mechanistic studies based on in situ infrared spectroscopy suggest a reaction pathway initiated through F-Si interactions. The activated phenylsilane allows for CO2 insertion to produce phenylsilyl formate, which undergoes attack by the amine to generate the target product.
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