The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. Category: amides-buliding-blocks, 617-45-8, Name is DL-Aspartic Acid, SMILES is NC(CC(O)=O)C(O)=O, in an article , author is Gomez-Calvario, Victor, once mentioned of 617-45-8.
Organoaluminum cations for carbonyl activation
In search of stable, yet reactive aluminum Lewis acids, we have isolated an organoaluminum cation, [(Me2NC6H4)(2)Al(C4H8O)(2)](+), coordinated with two labile tetrahydrofuran ligands. Its catalytic performance in aldehyde dimerization reveals turn-over frequencies reaching up to 6000 h(-1), exceeding that of the reported main group catalysts. The cation is further demonstrated to catalyze hydroelementation of ketones. Mechanistic investigations reveal that aldehyde dimerization and ketone hydrosilylation occur through carbonyl activation.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 617-45-8, you can contact me at any time and look forward to more communication. Category: amides-buliding-blocks.