Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Thi Hang Nga Nguyen, once mentioned the application of 86123-95-7, Name is (R)-2-((tert-Butoxycarbonyl)amino)-3-methoxypropanoic acid, molecular formula is C9H17NO5, molecular weight is 219.235, MDL number is MFCD08063987, category is amides-buliding-blocks. Now introduce a scientific discovery about this category, HPLC of Formula: C9H17NO5.
Nickel-Catalyzed Synthesis of N-Substituted Pyrroles Using Diols with Aryl- and Alkylamines
Herein, nickel-catalyzed sustainable strategy for the synthesis of N-substituted pyrroles using butene-1,4-diols and butyne-1,4-diols with a series of aryl-, alkyl-, and heteroarylamines is reported. The catalytic protocol is tolerant of free alcohol, halide, alkyl, alkoxy, oxygen heterocycles, activated benzyl, and the pyridine moiety and resulted in up to 90% yield. Initial mechanistic studies involving defined nickel catalyst, determination of rate, and order of reaction including deuterium-labeling experiments were performed for pyrrole synthesis.
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