Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 7396-58-9, Name is N-Decyl-N-methyldecan-1-amine, molecular formula is C21H45N. In an article, author is Mirjalili, BiBi Fatemeh,once mentioned of 7396-58-9, Formula: C21H45N.
Hydrogen bonding elements, pi – hole functional moieties and C(3)v tripodal scaffold controlled turn-on cyanide and turn-off azide selective receptors
Here in, we are reporting electron deficient amide and sulfonamide based tripodal receptors L, L-1,L-2 and L-3. Systematic studies show a strong selectivity towards cyanide and azide anions. Detailed UV-Visible and fluorescent spectrometric investigation shows the amide based tripodal receptors Land L-3 acts as a colori metric and turn-on fluorescent chemo-sensor for cyanide, and the sulfonamide based tripodal receptors L-1 and L-2 acts as a colorirnetric and turn-off fluorescent chemo-sensor for azide. At the end we have successfully prepared tripodal receptors for a particular anion with judicious choice of recognition elements such as hydrogen bonding amide/sulfonamide moiety, electron deficient pentafluorophenyl functionality for anion-pi interaction and the well defined C(3)v symmetric tripodal backbone for perfect recognition. (C) 2019 Elsevier B.V. All rights reserved.
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