Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, Quality Control of DL-Alanine302-72-7, Name is DL-Alanine, SMILES is NC(C)C(O)=O, belongs to amides-buliding-blocks compound. In a article, author is Gianessi, Carol A., introduce new discover of the category.
Ruthenium-Catalyzed C-H Benzoxylation of tert-Benzamides with Aromatic Acids by Weak Coordination
A highly regioselective C-H benzoxylation of tertiary benzamides with aromatic acids by weak O-amide coordination in the presence of [{RuCl2(p-cymene)}(2)], AgSbF6, and (NH4)2S(2)O(8) in 1,2-dichloroethane at 100 degrees C for 24 h to afford ortho-benzoxylated tertiary benzamides is described. Selectively, ortho-benzoxylated cyclic benzamides were converted into ortho-benzoxylated benzaldehydes by using Cp2ZrHCl at room temperature. Subsequently, substituted salicylic acids were prepared by deprotection of the ester and amide groups of ortho-benzoxylated cyclic benzamides.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 302-72-7. Quality Control of DL-Alanine.