In an article, author is Congdon, Molly D., once mentioned the application of 16066-84-5, Name: tert-Butyl methylcarbamate, Name is tert-Butyl methylcarbamate, molecular formula is C6H13NO2, molecular weight is 131.1729, MDL number is MFCD08899404, category is amides-buliding-blocks. Now introduce a scientific discovery about this category.
Transition metal-free aerobic oxidative cleavage of the C-N bonds of alpha-amino esters
An efficient transition metal-free cleavage of the C-N bonds of alpha-amino esters under mild conditions has been developed. The reaction was performed in the presence of KOtBu and molecular oxygen. Mechanistic studies reveal that the reaction proceeds through a base-mediated aerobic oxidative cleavage pathway involving the formation of a hydroperoxide intermediate.
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