In an article, author is Orton, Henry W., once mentioned the application of 98-10-2, Product Details of 98-10-2, Name is Benzenesulfonamide, molecular formula is C6H7NO2S, molecular weight is 157.1903, MDL number is MFCD00007930, category is amides-buliding-blocks. Now introduce a scientific discovery about this category.
Hydroxy Group Directed Catalytic Hydrosilylation of Amides
Chemo- and site-selective hydrosilylation of alpha or beta-hydroxy amides using organocatalyst B(C6F5)(3) and commercially available hydrosilanes is described. This transformation is operative under mild conditions and tolerates a wide range of functional groups. The reaction was applied for selective reduction of a specific amide group of the therapeutically important cyclic peptide cyclosporin A, demonstrating the potential usefulness of this catalytic method in late-stage structural transformations of drug lead molecules.
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