Related Products of 73942-87-7, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 73942-87-7, Name is 7,8-Dimethoxy-1,3-dihydro-2H-3-benzazepin-2-one, SMILES is O=C1NC=CC2=CC(OC)=C(OC)C=C2C1, belongs to amides-buliding-blocks compound. In a article, author is Sun, Rui, introduce new discover of the category.
Nickel/Briphos-Catalyzed Direct Transamidation of Unactivated Secondary Amides Using Trimethylsilyl Chloride
Direct transamidation of secondary amides was developed via nickel catalysis. In the presence of trimethylsilyl chloride and manganese, Ni(diglyme)Cl-2 with a Briphos ligand efficiently promoted the transamidation of N-aryl benzamide derivatives with primary amines to afford the corresponding secondary amides in moderate to good yields. Primary amines bearing electron-donating groups gave higher yields of the transamidation products.
Related Products of 73942-87-7, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 73942-87-7.