In an article, author is Kaminskyy, Danylo, once mentioned the application of 1314538-55-0, Safety of Potassium (((tert-butoxycarbonyl)amino)methyl)trifluoroborate, Name is Potassium (((tert-butoxycarbonyl)amino)methyl)trifluoroborate, molecular formula is C6H12BF3KNO2, molecular weight is 237.0695, MDL number is MFCD19686142, category is amides-buliding-blocks. Now introduce a scientific discovery about this category.
Prolinamides of Aminouracils, Organocatalyst Modifiable by Complementary Modules
We report the synthesis and evaluation of prolinamide organocatalysts that incorporate aminouracils. The features of these catalysts are enhanced NH acidity of the amide because of the electron-withdrawing nature of the heterocycle, an additional hydrogen-bond donor at the alpha or beta positions of this functional group (using 6-aminouracil or 5,6-diaminouracil respectively), and it can be recovered due to its low solubility and used again without decreasing the enantioselectivity. A unique feature of these systems is the self-assembly capability with complementary modules by Watson-Crick interactions. These supramolecular adducts behave differently from the catalyst alone, some of them have lower performance but others improve the selectivity of the product. Therefore, this approach avoids the synthesis of many catalysts.
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