Related Products of 2419-56-9, Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. 2419-56-9, Name is H-Glu(OtBu)-OH, SMILES is [H][C@](N)(CCC(=O)OC(C)(C)C)C(O)=O, belongs to amides-buliding-blocks compound. In a article, author is Shastri, Aparna, introduce new discover of the category.
Regiocontrolled Halogen Dance of Bromothiophenes and Bromofurans
The LDA (lithium diisopropylamide)-promoted regiocontrolled halogen dance of alpha-bromothiophenes and alpha-bromofurans is described. Bromothiophenes bearing a diethyl acetal moiety undergo selective deprotonation at the beta-position adjacent to the bromo group. In contrast, oxazoline, ester, and amide groups act as directing groups in the initial lithiation step to generate a carbanion at the beta-position neighboring the directing group to exclusively give the other regioisomer. These results can be applied to the regiocontrolled halogen dance of bromofuran derivatives.
Related Products of 2419-56-9, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 2419-56-9.