Electric Literature of 146374-27-8, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 146374-27-8, Name is 2-Methylpropane-2-sulfinamide, SMILES is CC(C)(C)[S](=O)N, belongs to amides-buliding-blocks compound. In a article, author is Liu, Changyao, introduce new discover of the category.
Amide-functionalized heterometallic helicate cages as highly efficient catalysts for CO2 conversion under mild conditions
Mimicking nature seems to be one of the smartest strategies to design novel catalysts for CO2 conversion under mild conditions. Herein, we report a facile and efficient method to construct two amide-functionalized heterometallic helicate cages as enzyme mimic catalysts for the synthesis of cyclic carbonates. These helicate cages show high thermal stability and exceptionally high catalytic activity and size-dependent selectivity toward small epoxides in catalytic CO2 cycloaddition to obtain cyclic carbonates even under ambient conditions. The construction of this novel functionalized cage provides an efficient approach for realizing CO2 conversion under mild conditions.
Electric Literature of 146374-27-8, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 146374-27-8.