Application of 27532-96-3, Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. 27532-96-3, Name is H-Gly-OtBu.HCl, SMILES is O=C(OC(C)(C)C)CN.[H]Cl, belongs to amides-buliding-blocks compound. In a article, author is Blessborn, Daniel, introduce new discover of the category.
Dinuclear Molybdenum(II) Complexes with Thioether Functionalized Silylamide Ligands
Treatment of molybdenum(II) acetate with thioether functionalized silylamides R2Si(NLi-C6H4-2-SR ‘)(2) leads to the formation of dinuclear Mo-II complexes [Mo-2{R2Si(NC6H4-2-SR ‘)(2)}(2)]. According to X-ray crystal structure analyses the complexes [Mo-2{Me2Si(NC6H4-2-SMe)(2)}(2)] and [Mo-2{Ph2Si(NC6H4-2-SPh)(2)}(2)] comprise a Mo-2-unit which is coordinated by two mu-kappa-N,N ‘ silylamide ligands. The coordination sphere around the molybdenum atoms consists of two amide nitrogen atoms and two thioether sulfur atoms in a distorted square-planar arrangement. The Mo-Mo distances are 211.0(1) and 211.7(1) pm, resp. In the complex [Mo-2{Ph2Si(NC6H4-2-SMe)(2)}(2)] the silyl amide units act as tetradentate kappa-N,N ‘,S,S ‘ chelating ligands and the Mo-Mo distance is 218.6(1) pm.
Application of 27532-96-3, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 27532-96-3 is helpful to your research.